Fluorescent mono- and tetra-dansylated cavitands: synthesis and acid sensitivity

被引：1

作者：

Isci, Umit ^{[1
]}

Zorlu, Yunus ^{[1
]}

Dumoulin, Fabienne ^{[1
]}

机构：

[1] Gebze Tech Univ, Dept Chem, Gebze, Turkey

来源：

TURKISH JOURNAL OF CHEMISTRY | 2015年 / 39卷 / 02期

关键词：

Resorcinarene; cavitand; dansyl; fluorescence; acid sensor; CALIXARENES; INCLUSION;

D O I：

10.3906/kim-1406-30

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two fluorescent tetra- and mono-dansylated resorcinarene cavitands were prepared and fully characterized. The X-ray structure of mono-dansylated resorcinarene cavitand was obtained. Their intrinsic absorption and fluorescence properties were studied. These properties were strongly sensitive to the presence of perchloric acid, as evidenced by the appearance of isobestic points upon protonation of the dansyl dimethylamino functions. The decreasing of the fluorescence emission intensity upon titration with perchloric acid was explained by the excited state interactions between the dansyl groups of the resorcinarene. Fluorescence quantum yields (Phi(F)) of mono- and tetra-dansylated cavitands and the reference compound were determined using dansyl chloride as reference in acetonitrile.

引用

页码：207 / 216

页数：10

共 50 条

[21] Synthesis, structure and dioxygen reactivity of Ni(II) complexes with mono-, bis-, tetra- and hexa-oxime ligands
Boyko, Yaroslav D.
Sukhorukov, Alexey Yu.
Semakin, Artem N.
Nelyubina, Yulia V.
Ananyev, Ivan V.
Rangappa, K. S.
Ioffe, Sema L.
POLYHEDRON, 2014, 71 : 24 - 33
[22] Synthesis of mono- and tetra-nuclear β-pyridylenolate zinc complexes and their catalysis toward the ring-opening copolymerization of ε-caprolactone and lactide
Qin, Lu
Bai, Jianliang
Zhang, Yue
Chen, Xia
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2018, 871 : 40 - 47
[23] Steric Control in the Synthesis of Phosphinous Acid-Coordinated Mono- and Binuclear Platinum(II) Complexes
Achard, Thierry
Giordano, Laurent
Tenaglia, Alphonse
Gimbert, Yves
Buono, Gerard
ORGANOMETALLICS, 2010, 29 (17) : 3936 - 3950
[24] SYNTHESIS AND THERAPEUTIC TESTING OF MONO- AND DIALKYL ESTERS OF PENTETIC (DIETHYLENETRIAMINEPENTAACETIC) ACID FOR DECORPORATION OF POLYMERIC PLUTONIUM
GUILMETTE, RA
PARKS, JE
LINDENBAUM, A
JOURNAL OF PHARMACEUTICAL SCIENCES, 1979, 68 (02) : 194 - 196
[25] Sulfamic acid: A green and efficient catalyst for synthesis of mono-, bis-, and spiro-perimidines
Bodaghifard, Mohammad Ali
Ahadi, Najmieh
IRANIAN JOURNAL OF CATALYSIS, 2016, 6 (04): : 377 - 380
[26] 9-Anthracenecarboxamide fluorescent probes for selective discrimination of picric acid from mono- and di-nitrophenols in ethanol
Pandith, Anup
Kumar, Ashwani
Lee, Ju-Young
Kim, Hong-Seok
TETRAHEDRON LETTERS, 2015, 56 (51) : 7094 - 7099
[27] Mono-, Di- and Tetra-iron Complexes with Selenium or Sulphur Functionalized Vinyliminium Ligands: Synthesis, Structural Characterization and Antiproliferative Activity
Agonigi, Gabriele
Batchelor, Lucinda K.
Ferretti, Eleonora
Schoch, Silvia
Bortoluzzi, Marco
Braccini, Simona
Chiellini, Federica
Biancalana, Lorenzo
Zacchini, Stefano
Pampaloni, Guido
Sarkar, Biprajit
Dyson, Paul J.
Marchetti, Fabio
MOLECULES, 2020, 25 (07):
[28] Enzymatic synthesis of mono- and disubstituted phospholipids by direct condensation of oleic acid and glycerophosphocholine with immobilized lipases and phospholipase
Garcia-Quinto, Ernestina
Garcia-Garcia, Paz
Guisan, Jose M.
Fernandez-Lorente, Gloria
FOOD CHEMISTRY, 2023, 401
[29] Efficient Synthesis of Optically Pure Mono- and Binuclear Macrocyclic Polylactones from Castor Oil and Sebacic Acid
Ishmuratov, G. Yu.
Medvedeva, N. I.
Saitov, K. M.
Yakovleva, M. P.
Nazarov, I. S.
Tolstikov, A. G.
DOKLADY CHEMISTRY, 2023, 513 (01) : 315 - 320
[30] Lewis acid-mediated synthesis of mono- and tris-indole adducts from chiral aziridines
Macha, Lingamurthy
Singh, Deepak
Rhee, Hyong-Jin
Ha, Hyun-Joon
ORGANIC & BIOMOLECULAR CHEMISTRY, 2020, 18 (46) : 9473 - 9482

← 1 2 3 4 5 →