Vinylcyclopropyl TMM diyls: access to eight-membered rings

被引：7

作者：

Mikesell, PJ ^{[1
]}

Little, RD ^{[1
]}

机构：

[1] Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 25期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0040-4039(01)00669-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Vinylcyclopropyl substituted diazenes (e.g. 1 and 15) rearrange when healed. The chemistry takes place via the formation of a trimethylenemethane (TMM) diyl and provides access to eight-membered rings. When the cyclopropane is fused to a five-membered ring (e.g. 15) rearrangement leads to a structure resembling the taxotere framework. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：4095 / 4097

页数：3

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