Reversible and Irreversible Electric Field Induced Morphological and Interfacial Transformations of Hybrid Lead Iodide Perovskites

被引:25
|
作者
Luchkin, Sergey Yu. [1 ]
Akbulatov, Azat F. [2 ]
Frolova, Lyubov A. [2 ]
Griffin, Monroe P. [3 ]
Dolocan, Andrei [4 ]
Gearba, Raluca [4 ]
Vanden Bout, David A. [3 ]
Troshin, Pavel A. [1 ,2 ]
Stevenson, Keith J. [1 ]
机构
[1] Skolkovo Inst Sci & Technol, Ctr Electrochem Energy Storage, Nobel St 3, Moscow 143026, Russia
[2] Russian Acad Sci, Inst Problems Chem Phys, Semenov Prospect 1, Chernogolovka 141432, Russia
[3] Univ Texas Austin, Dept Chem, Austin, TX 78712 USA
[4] Univ Texas Austin, Texas Mat Inst, Austin, TX 78712 USA
关键词
MAPbI(3)solar cells; hybrid perovskites; electric field; degradation; ION MIGRATION; SOLAR-CELLS; DEGRADATION;
D O I
10.1021/acsami.7b01960
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
We report reversible and irreversible strain effects, and interfacial atomic mixing in MAPbI(3)/ITO under influence of external electric bias and photoillumination. Using conductive-probe atomic force microscopy, we locally applied a bias voltage between the MAPbI(3)/ITO and the conductive tip and observed local dynamic strain effects and current under conditions of forward bias. We found that the reversible part of the strain is associated with a current spike at the current onset stage and can therefore be related to an electrochemical process accompanied by local molar volume change. Similar partly reversible surface deformation was observed when the tip-sample contact was illuminated by light. Time-of-flight secondary ion mass spectrometry of electrically biased regions revealed massive atomic mixing at the buried MAPbI(3)/ITO interface, while the top MAPbI(3) surface, subjected to strong morphological damage at the tip-surface contact, revealed less significant chemical decomposition.
引用
收藏
页码:33478 / 33483
页数:6
相关论文
共 50 条
  • [31] Accelerated degradation of methylammonium lead iodide perovskites induced by exposure to iodine vapour
    Shenghao Wang
    Yan Jiang
    Emilio J. Juarez-Perez
    Luis K. Ono
    Yabing Qi
    Nature Energy, 2
  • [32] REVERSIBLE AND IRREVERSIBLE ROTATING FIELD-INDUCED MEMBRANE MODIFICATIONS
    FUHR, G
    MULLER, T
    HAGEDORN, R
    BIOCHIMICA ET BIOPHYSICA ACTA, 1989, 980 (01) : 1 - 8
  • [33] Electric-field effect on photoluminescence of lead-halide perovskites
    Yi, Hee Taek
    Rangan, Sylvie
    Tang, Boxin
    Frisbie, C. Daniel
    Bartynski, Robert A.
    Gartstein, Yuri N.
    Podzorov, Vitaly
    MATERIALS TODAY, 2019, 28 : 31 - 39
  • [34] Electric-Field-Induced Organic Transformations
    Kareem, Shaik
    Vali, Shaik Ramjan
    Reddy, B. V. Subba
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2023, 26 (20)
  • [35] REVERSIBLE AND IRREVERSIBLE MODIFICATION OF ERYTHROCYTE-MEMBRANE PERMEABILITY BY ELECTRIC-FIELD
    SERPERSU, EH
    KINOSITA, K
    TSONG, TY
    BIOCHIMICA ET BIOPHYSICA ACTA, 1985, 812 (03) : 779 - 785
  • [36] Electric-field-induced aging dynamics of triple-cation lead iodide perovskite at nanoscale
    Emelianov, Nikita A.
    Ozerova, Victoria V.
    Fedotov, Yuri S.
    Shchurik, Elena V.
    Slesarenko, Nikita A.
    Zhidkov, Mikhail V.
    Golosov, Eugeniy V.
    Saifutyarov, Rasim R.
    Frolova, Lyubov A.
    Troshin, Pavel A.
    SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2025, 282
  • [37] Proton Migration in Hybrid Lead Iodide Perovskites: From Classical Hopping to Deep Quantum Tunneling
    Feng, Yexin
    Zhao, Yicheng
    Zhou, Wen-Ke
    Li, Qi
    Saidi, Wissam A.
    Zhao, Qing
    Li, Xin-Zheng
    JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2018, 9 (22): : 6536 - 6543
  • [38] Passivation by pyridine-induced PbI2in methylammonium lead iodide perovskites
    Cook, Andre
    Jones, Timothy W.
    Wang, Jacob Tse-Wei
    Li, Hua
    Atkin, Rob
    Duffy, Noel W.
    Donne, Scott W.
    Wilson, Gregory J.
    RSC ADVANCES, 2020, 10 (40) : 23829 - 23833
  • [39] Electric field-induced irreversible phase transformations in Pb(Zr, Ti) O3-based piezoceramics
    Kalyani, Ajay Kumar
    Kumar, Ajeet
    James, A. R.
    SOLID STATE COMMUNICATIONS, 2023, 361
  • [40] Reversible Laser-Induced Amplified Spontaneous Emission from Coexisting Tetragonal and Orthorhombic Phases in Hybrid Lead Halide Perovskites
    Panzer, Fabian
    Baderschneider, Sebastian
    Gujar, Tanaji P.
    Unger, Thomas
    Bagnich, Sergey
    Jakoby, Marius
    Baessler, Heinz
    Huettner, Sven
    Koehler, Jurgen
    Moos, Ralf
    Thelakkat, Mukundan
    Hildner, Richard
    Koehler, Anna
    ADVANCED OPTICAL MATERIALS, 2016, 4 (06): : 917 - 928