Syntheses of optically active 2-substituted cyclopropanecarboxylic acids from chiral α-hydroxysilane derivatives

被引：30
|
作者：
Sakaguchi, K [1 ]
Mano, H [1 ]
Ohfune, Y [1 ]
机构：
[1] Osaka City Univ, Dept Mat Sci, Grad Sch Sci, Sumiyoshi Ku, Osaka 5588585, Japan
来源：
TETRAHEDRON LETTERS | 1998年 / 39卷 / 24期
关键词：
masked chirality; alpha-hydroxysilane; optically active cyclopropanecarboxylic acid; diastereoselective cyclopropanation;
D O I：
10.1016/S0040-4039(98)00759-X
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Optically active 2-alkylcyclopropanecarboxylic acids were efficiently synthesized from the chiral alpha-hydroxytrimethylsilanes via a diastereoselective cyclopropanation as the key step, (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：4311 / 4312
页数：2
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