Acceleration of a hetero-Diels-Alder reaction by cyclic metalloporphyrin trimers

被引：74

作者：

Marty, M ^{[1
]}

Clyde-Watson, Z ^{[1
]}

Twyman, LJ ^{[1
]}

Nakash, M ^{[1
]}

Sanders, JKM ^{[1
]}

机构：

[1] Univ Cambridge, Cambridge Ctr Mol Recognit, Chem Lab, Cambridge CB2 1EW, England

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 20期

关键词：

D O I：

10.1039/a806070c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The hetero-Diels-Alder reaction between a pyridylbutadiene and 3-nitrosopyridine is accelerated by a variety of metalloporphyrin trimers; there is a weak correlation between rate acceleration and product binding strength.

引用

页码：2265 / 2266

页数：2

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