A facile one-step synthesis of polymer supported rhodium nanoparticles in organic medium and their catalytic performance in the dehydrogenation of ammonia-borane

被引：46
|
作者：
Karahan, Senem [1 ]
Zahmakiran, Mehmet [1 ]
Ozkar, Saim [1 ]
机构：
[1] Middle E Tech Univ, Dept Chem, TR-06531 Ankara, Turkey
来源：
CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 08期
关键词：
HYDROGEN GENERATION; NANOCLUSTERS CATALYST; HYDROLYSIS; BORON; STABILIZATION; DISSOCIATION; CARBON;
D O I：
10.1039/c1cc15864c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new type of supported rhodium nanoparticles were reproducibly prepared from N2H4BH3 reduction of [Rh(mu-Cl)(1,5-cod)](2) without using any solid support and pre-treatment technique. Their characterization shows the formation of well dispersed rhodium(0) nanoparticles within the framework of a polyaminoborane based polymeric support. These new rhodium(0) nanoparticles were found to be the most active supported catalyst in the catalytic dehydrogenation of ammonia-borane in water at room temperature.
引用
收藏
页码：1180 / 1182
页数：3
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