A facile one-step synthesis of polymer supported rhodium nanoparticles in organic medium and their catalytic performance in the dehydrogenation of ammonia-borane

被引：46

作者：

Karahan, Senem ^{[1
]}

Zahmakiran, Mehmet ^{[1
]}

Ozkar, Saim ^{[1
]}

机构：

[1] Middle E Tech Univ, Dept Chem, TR-06531 Ankara, Turkey

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 08期

关键词：

HYDROGEN GENERATION; NANOCLUSTERS CATALYST; HYDROLYSIS; BORON; STABILIZATION; DISSOCIATION; CARBON;

D O I：

10.1039/c1cc15864c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new type of supported rhodium nanoparticles were reproducibly prepared from N2H4BH3 reduction of [Rh(mu-Cl)(1,5-cod)](2) without using any solid support and pre-treatment technique. Their characterization shows the formation of well dispersed rhodium(0) nanoparticles within the framework of a polyaminoborane based polymeric support. These new rhodium(0) nanoparticles were found to be the most active supported catalyst in the catalytic dehydrogenation of ammonia-borane in water at room temperature.

引用

页码：1180 / 1182

页数：3

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