Synthesis of novel mercaptophenyl carbocyclic C-nucleoside analogue using sequential [3,3]-sigmatropic rearrangement and ring-closing metathesis

被引：0

作者：

Li, Hua ^{[1
]}

Hong, Joon Hee ^{[1
]}

机构：

[1] Chosun Univ, Coll Pharm, Project Team BK 21, Kwangju 501759, South Korea

来源：

BULLETIN OF THE KOREAN CHEMICAL SOCIETY | 2008年 / 29卷 / 04期

关键词：

carbocyclic C-nucleoside; 3,3]-sigmatropic rearrangement; ring-closing metathesis; Friedel-Crafts alkylation;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Novel mercaptophenyl carbocyclic C-nucleoside analogue was synthesized via a cyclopentenol intermediate 10, which was prepared using a sequential [3,3]-sigmatropic rearrangement and ring-closing metathesis (RCM). Friedel-Crafts alkylation was then used to couple the thiophenol.

引用

页码：847 / 850

页数：4

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