Molecular porphyrin-fullerene architectures

被引:111
|
作者
Guldi, DM [1 ]
机构
[1] Univ Notre Dame, Radiat Lab, Notre Dame, IN 46556 USA
关键词
D O I
10.1351/pac200375081069
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
This article describes the utilization of porphyrin and fullerene architectures-yielding artificial light-harvesting antenna and reaction center mimics-to tune the electronic coupling element between electron donor and electron acceptor and ultimately to affect the total reorganization energy. Most importantly, the effects that these parameters have on the rate, yield, and lifetime of the energetic charge-separated states are discussed.
引用
收藏
页码:1069 / 1075
页数:7
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