Diphosphine sulfides derived from 2,2′-biphosphole:: novel chiral S,S ligands for palladium-catalyzed asymmetric allylic substitution

被引：6

作者：

Robe, Emmanuel ^{[1
]}

Perlikowska, Wieslawa ^{[2
]}

Lemoine, Celine ^{[1
]}

Diab, Lisa ^{[1
]}

Vincendeau, Sandrine ^{[1
]}

Mikolajczyk, Marian ^{[2
]}

Daran, Jean-Claude ^{[1
]}

Gouygou, Maryse ^{[1
]}

机构：

[1] CNRS, Chim Coordinat Lab, F-31007 Toulouse, France

[2] Polish Acad Sci, Ctr Mol & Macromol Studies, PL-90363 Lodz, Poland

来源：

DALTON TRANSACTIONS | 2008年 / 21期

关键词：

D O I：

10.1039/b719554k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Diphosphine sulfides derived from 2,2'-biphosphole have been efficiently synthesized in an enantiomerically pure form by a four step synthetic sequence. These S,S-ligands were used for the first time in Pd-catalyzed asymmetric allylic alkylation. Good yields and enantiomeric excess up to 73% were obtained.

引用

页码：2894 / 2898

页数：5

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