La2Sb, a layered superconductor with metal-metal bonds

被引：9
|
作者：
Mizoguchi, Hiroshi [1 ]
Hosono, Hideo [1 ,2 ]
机构：
[1] Tokyo Inst Technol, Frontier Res Ctr, Midori Ku, Yokohama, Kanagawa 2268503, Japan
[2] Tokyo Inst Technol, Mat & Struct Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan
来源：
CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 13期
关键词：
CRYSTAL-STRUCTURE;
D O I：
10.1039/c0cc05384h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We found that La2Sb with a layered structure composed of alternate stacking of La square nets and LaSb layers exhibits bulk superconductivity with a critical temperature of 5.3 K. This suggests that the presence of the square net with strong La-La metal bonding is essential for the emergence of superconductivity.
引用
收藏
页码：3778 / 3780
页数：3
相关论文
共 50 条
  • [31] CATALYTIC ACTIVITY BY OPENING OF METAL-METAL BONDS
    LANGENBACH, HJ
    KELLER, E
    VAHRENKAMP, H
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1977, 16 (03): : 188 - 189
  • [32] PLANAR COMPLEXES CONTAINING METAL-METAL BONDS
    KROGMANN, K
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1969, 8 (01) : 35 - &
  • [33] Mixed valency and metal-metal quadruple bonds
    Chisholm, Malcolm H.
    COORDINATION CHEMISTRY REVIEWS, 2013, 257 (9-10) : 1576 - 1583
  • [34] Oligothiophenes incorporating metal-metal quadruple bonds
    Chisholm, MH
    Epstein, AJ
    Gallucci, JC
    Feil, F
    Pirkle, W
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (40) : 6537 - 6540
  • [35] Adventures with stronger and weaker metal-metal bonds
    Maverick, Andrew
    Butler, Leslie
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2016, 251
  • [36] GEOMETRIC ISOMERISM BASED ON METAL-METAL BONDS
    FENG, Q
    RAUCHFUSS, TB
    WILSON, SR
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (16) : 4702 - 4703
  • [37] REACTIVITY OF METAL-METAL BONDS .V.
    BEVERIDGE, AD
    CLARK, HC
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1968, 11 (03) : 601 - +
  • [38] Chiral molecules containing metal-metal bonds
    Cotton, F. Albert
    Murillo, Carlos A.
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2006, (21) : 4209 - 4218
  • [39] Triosmium sulfate complexes with metal-metal bonds
    Zhilyaev, AN
    Katser, SB
    Fomina, TA
    ZHURNAL NEORGANICHESKOI KHIMII, 1996, 41 (05): : 759 - 765
  • [40] Pyramidality effect on metal-metal single bonds
    Aullon, G
    Alvarez, S
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (15): : 2681 - 2687
12345