Non-toxic poly(ethylene terephthalate)/clay nanocomposites with enhanced barrier properties

被引：18
|
作者：
Hayrapetyan, Suren [1 ]
Kelarakis, Antonios [1 ]
Estevez, Luis [1 ]
Lin, Qin [1 ]
Dana, Kausik [1 ]
Chung, Yi-Lin [1 ]
Giannelis, Emmanuel P. [1 ]
机构：
[1] Cornell Univ, Dept Mat Sci & Engn, Ithaca, NY 14853 USA
来源：
POLYMER | 2012年 / 53卷 / 02期
基金：
美国国家科学基金会;
关键词：
Poly(ethylene terephthalate); Barrier properties; Non-toxic; NONISOTHERMAL CRYSTALLIZATION KINETICS; THERMAL-DEGRADATION; MELTING BEHAVIOR; CLAY; PET; POLY(ETHYLENE-TEREPHTHALATE); IMIDAZOLIUM; MORPHOLOGY; MECHANISMS; TOXICITY;
D O I：
10.1016/j.polymer.2011.12.017
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Motivated by the technological need for poly(ethylene terephthalate) materials with improved barrier properties together with the requirement for sustainability this study focuses on an eco-friendly sulfonated polyester as clay compatibilizer to facilitate polymer mixing during melt compounding. We demonstrate that the nanocomposites based on sulfonated polyester are a reliable alternative to their imidazolium counterparts, exhibiting enhanced properties (water vapor and UV transmission), without sacrificing the excellent transparency, clarity and mechanical strength of the matrix. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码：422 / 426
页数：5
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