Synthesis, electrochemical and spectroscopic properties of ferrocene-based compounds

被引：0

作者：

Onel, Gulce Taskor ^{[1
]}

Karaaslan, Emine Ozgul ^{[2
]}

Osken, Ipek ^{[3
]}

Saygili, Nezire ^{[4
]}

机构：

[1] Erzincan Binali Yildirim Univ, Fac Pharm, Dept Basic Pharmaceut Sci, TR-24100 Erzincan, Turkey

[2] Kirikkale Univ, Fac Art & Sci, Dept Chem, TR-71450 Kirikkale, Turkey

[3] Istanbul Tech Univ, ITU Aerosp Res Ctr, TR-34469 Istanbul, Turkey

[4] Hacettepe Univ, Fac Pharm, Dept Basic Pharmaceut Sci, TR-06100 Ankara, Turkey

来源：

CHEMICAL PAPERS | 2022年 / 76卷 / 04期

关键词：

Ferrocene derivatives; Palladium catalyst; Cross-coupling; UV-vis spectroscopy; Cyclic voltammetry; STRUCTURAL-CHARACTERIZATION; ETHYL-ESTERS; DERIVATIVES; ACID; COMPLEXES; CHEMISTRY; CRYSTAL; LIGANDS;

D O I：

10.1007/s11696-021-02034-7

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ferrocene derivatives have been synthesized by the Suzuki cross-coupling reaction of ferroceneboronic acid with various aryl/heteroaryl halides. The reactions yield ferrocenyl derivatives with overall yields varying between 35 and 98%. The derivatives have been characterized by (HNMR)-H-1, C-13 NMR, IR, HRMS and elemental analysis. The structure-property relationship has been investigated based on UVNis spectroscopy and cyclic voltammetry. Cyclic voltammetry studies revealed when the side group of ferrocenes were an electron-donating, lower oxidation was displayed. On the other hand, the strong electron-withdrawing group had a higher oxidation potential. [GRAPHICS] .

引用

页码：2249 / 2257

页数：9

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