The first phosphine oxide ligand precursors for transition metal catalyzed cross-coupling reactions: C-C, C-N, and C-S bond formation on unactivated aryl chlorides

被引：0
|
作者：
Li, GY [1 ]
机构：
[1] Dupont Co, Cent Res & Dev, Expt Stn, Wilmington, DE 19880 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2001年 / 40卷 / 08期
关键词：
D O I：
10.1002/1521-3773(20010417)40:8<1513::AID-ANIE1513>3.0.CO;2-C
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Rapid and regioselective oxidative addition of unactivated aryl chlorides in the presence of bases can be achieved by using metal complexes of phosphinous acid (RR′POH), for which air-stable phosphine oxides (RR′P(O)H) serve as ideal ligand precursors. Such processes can be incorporated into efficient catalytic cycles for a variety of C-C, C-N, and C-S bond-forming processes (see scheme, Ar = aryl).
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页码：1513 / +
页数：5
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