Synthesis of natural products by rhodium-mediated intramolecular C-H insertion

被引：0
|
作者：
Taber, DF [1 ]
Stiriba, SE
机构：
[1] Univ Delaware, Dept Chem & Biochem, Newark, DE 19716 USA
[2] Univ Valencia, Dept Quim Inorgan, E-46100 Valencia, Spain
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 1998年 / 4卷 / 06期
关键词：
C-C coupling; cyclizations; diazo compounds; natural products; rhodium;
D O I：
10.1002/(SICI)1521-3765(19980615)4:6<990::AID-CHEM990>3.0.CO;2-U
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Rh-mediated intramolecular C-H insertion allows the direct construction of carbon - carbon bonds at previously unactivated centers. The natural product syntheses described here highlight the strategic advantages and efficiencies this reaction offers.
引用
收藏
页码：990 / 992
页数：3
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