Metal-Free Transfer Hydrogenation Catalysis by B(C6F5)3

被引：91
|
作者：
Farrell, Jeffrey M. [1 ]
Heiden, Zachariah M. [1 ]
Stephan, Douglas W. [1 ]
机构：
[1] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada
来源：
ORGANOMETALLICS | 2011年 / 30卷 / 17期
基金：
加拿大自然科学与工程研究理事会;
关键词：
DYNAMIC KINETIC RESOLUTION; CHIRAL AMINES; RACEMIZATION; IMINES; REDUCTION; PHOSPHINES; REACTIVITY; DIHYDROGEN; ACTIVATION; ALCOHOLS;
D O I：
10.1021/om2005832
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The activation of amines by B(C6F5)(3) is shown to effect the catalytic racemization of a chiral amine. Extending this strategy to a bimolecular process, catalytic transfer hydrogenation of imines, enamines, and N-heterocycles is demonstrated using iPr(2)NH as the source of hydrogen and a catalytic amount of the Lewis acid B(C6F5)(3).
引用
收藏
页码：4497 / 4500
页数：4
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