An efficient synthesis of alkyl substituted cyclic 1,3-diones

被引：0

作者：

Pashkovsky, FS ^{[1
]}

Lokot, IP ^{[1
]}

Lakhvich, FA ^{[1
]}

机构：

[1] Natl Acad Sci Belarus, Inst Bioorgan Chem, Minsk 220141, BELARUS

来源：

SYNLETT | 2001年 / 09期

关键词：

cyclic beta.beta '-triones; sodium cyanoborohydride; selective reduction; cyclic alpha-alkyl beta-diones;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient method for the synthesis of cyclic alpha -alkyl beta -dicarbonyl compounds of cyclopentane, cyclohexane, tetronic acid and alpha -pyrone series is described. The method consists of the selective transformation of the corresponding cyclic beta,beta ' -tricarbonyl compounds by NaBH3CN in a mixture of THF and 2N aqueous HCl.

引用

页码：1391 / 1394

页数：4

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