Enhanced Charge Separation in Ternary Bulk-Heterojunction Organic Solar Cells by Fullerenes

Carrier generation dynamics in binary PTB7-Th:CO(i)8DFIC (1:1.5) and ternary PTB7-Th:CO(i)8DFIC:PC71BM (1:1.05:0.45) composites were investigated to identify the origins of high power conversion efficiencies (PCEs) in ternary bulk-heterojunction (BHJ) organic solar cells. Steady-state photoluminescence and time-resolved photoinduced absorption spectroscopic analyses revealed that the ternary composite exhibited faster hole transfer from CO(i)8DFIC to PTB7-Th (8 ps compared to 21 ps in the binary composite), which led to an improved exciton separation yield in CO(i)8DFIC (94% compared to 68% in the binary composite). Improved intermixing of the component materials and efficient electron transfer from CO(i)8DFIC to PC71BM facilitated enhancement in the hole transfer rate. The CO(i)8DFIC-to-PC71BM electron transfer promoted an electron transport cascade over PTB7-Th, CO(i)8DFIC, and PC71BM, which efficiently deactivated back-electron transfer (carrier recombination loss) from CO(i)8DFIC to PTB7-Th at similar to 160 ps and assisted in improving the PCE of the ternary BHJ cell (13.4% compared to 10.5% in the binary BHJ cell).