Synthesis and spectroscopic [IR, NMR (1H, 13C, 29Si)] characterization of methylsilyl N-arylsalicylaldiminates

被引：12
|
作者：
Goyal, M [1 ]
Mishra, S [1 ]
Singh, A [1 ]
机构：
[1] Univ Rajasthan, Dept Chem, Jaipur 302004, Rajasthan, India
来源：
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2001年 / 175卷
关键词：
methylsilyl compounds; Schiff base complexes; N-arylsalicylaldiminates;
D O I：
10.1080/10426500108040262
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reactions of MeSiCl3 in 1:1, 1:2, and 1:3 molar ratios with HOC6H4CH=NAr (Ar = C6H3Me2-2,6; C6H2Me3-2,4,6; and C6H3Et2-2,6) in the presence of Et3N or C5H5N as a base afford compounds of the type MeSiCl3-x(OC6H4CH=NAr)(x) (x = 1, 2, and 3). Characterization of all these species have been carried out by elemental analysis, molecular weight determinations, and spectroscopic [IR, NMR (H-1, C-13 and Si-29)] studies.
引用
收藏
页码：143 / 152
页数：10
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