Synthesis and spectroscopic [IR, NMR (1H, 13C, 29Si)] characterization of methylsilyl N-arylsalicylaldiminates

被引：12
|
作者：
Goyal, M [1 ]
Mishra, S [1 ]
Singh, A [1 ]
机构：
[1] Univ Rajasthan, Dept Chem, Jaipur 302004, Rajasthan, India
来源：
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2001年 / 175卷
关键词：
methylsilyl compounds; Schiff base complexes; N-arylsalicylaldiminates;
D O I：
10.1080/10426500108040262
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reactions of MeSiCl3 in 1:1, 1:2, and 1:3 molar ratios with HOC6H4CH=NAr (Ar = C6H3Me2-2,6; C6H2Me3-2,4,6; and C6H3Et2-2,6) in the presence of Et3N or C5H5N as a base afford compounds of the type MeSiCl3-x(OC6H4CH=NAr)(x) (x = 1, 2, and 3). Characterization of all these species have been carried out by elemental analysis, molecular weight determinations, and spectroscopic [IR, NMR (H-1, C-13 and Si-29)] studies.
引用
收藏
页码：143 / 152
页数：10
相关论文
共 50 条
  • [1] Synthesis, reactions, and spectral [NMR (1H, 13C, 29Si) IR] studies of trimethylsilyl-substituted N-arylsalicylaldiminates
    Goyal, M
    Mishra, S
    Singh, A
    SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 2001, 31 (09): : 1705 - 1715
  • [2] Synthesis, reactions, and spectral [NMR(1H, 13C, and 29Si), IR] studies of organosilicon aryloxides
    Mishra, S
    Singh, A
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 2001, 40 (07): : 772 - 774
  • [3] 29Si, 13C, 1H NMR of some di-tert-butylsilanes.
    Liu, M
    Fuller-Stanley, J
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1998, 215 : U209 - U209
  • [4] NMR Study (1H, 13C, 29Si) of Derivations of Acetylene Silicides by SPI.
    Bennetau, B.
    Birot, M.
    Deleris, G.
    Dunogues, J.
    Pillot, J.-P
    Barbe, B.
    Petraud, M.
    Reviews on silicon, germanium, tin and lead compounds, 1985, 8 (04): : 327 - 348
  • [5] Synthesis and spectroscopic (IR,1H,13C and 29Si) studies on some configurational isomers of triorganosilicon (IV) complexes of N-(alkyl)-2-mercaptoacetamides
    Singh, R
    Sharma, RK
    Singh, Y
    Rai, AK
    MAIN GROUP METAL CHEMISTRY, 2000, 23 (04): : 233 - 237
  • [6] 1H, 13C and 29Si magnetic shielding in gaseous and liquid tetramethylsilane
    Makulski, Wlodzimierz
    Jackowski, Karol
    JOURNAL OF MAGNETIC RESONANCE, 2020, 313
  • [7] Preparation of carbosilane dendrimers and their characterization using 1H/13C/29Si triple resonance 3D NMR methods
    Chai, MH
    Pi, ZJ
    Tessier, C
    Rinaldi, PL
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (02) : 273 - 279
  • [8] Pauling Electronegativity On/Off Effects Assessed by 13C and 29Si NMR Spectroscopic Analysis
    Benedetti, Michele
    De Castro, Federica
    Fanizzi, Francesco P.
    CHEMISTRY-A EUROPEAN JOURNAL, 2017, 23 (66) : 16877 - 16884
  • [9] Synthesis and spectroscopic (IR and 1H, 13C, 27Al NMR) characterization of several aluminium and gallium N-arylsalicylaldiminate derivatives
    Goyal, M
    Mishra, S
    Singh, A
    MAIN GROUP METAL CHEMISTRY, 2001, 24 (12) : 829 - 834
  • [10] 1H and 13C NMR spectroscopic characterization of poly(amide-enaminonitriles)
    Moore, JA
    Kaur, S
    MACROMOLECULES, 2000, 33 (10) : 3585 - 3589
12345