Electrochemical Studies of Inhibition of Zinc Corrosion in Hydrochloric Acid by Phosphonium Salts

被引:1
|
作者
Harvey, T. J. [1 ]
Walsh, F. C. [1 ,2 ,3 ]
Nahle, A. H. [4 ]
机构
[1] Univ Southampton, Engn Sci, Natl Ctr Adv Tribol Southampton, Southampton SO17 1BJ, Hants, England
[2] Univ Southampton, Electrochem Engn Lab, Southampton SO17 1BJ, Hants, England
[3] Univ Southampton, Mat Engn Res Grp, Engn Sci, Southampton SO17 1BJ, Hants, England
[4] Univ Sharjah, Coll Sci, Dept Chem, POB 27272, Sharjah, U Arab Emirates
关键词
adsorption; polarisation; Tafel region; voltammetry; CARBON-STEEL CORROSION; 1N HCL SOLUTION; MILD-STEEL; ADSORPTION; BEHAVIOR; NICKEL; OIL; DERIVATIVES; MECHANISM; BROMIDE;
D O I
10.3103/S106837552002009X
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The performance of five synthesised phosphonium salts, 4-tolyltriphenyl-phosphonium chloride (TTPPC), 4-phenoltriphenylphosphonium chloride (PTPPC), 4-anilinetriphenylphosphonium bromide (ATPPB), 4-benzyl alcoholtriphenylphosphonium chloride (BATPPC), 4-chlorophenyltriphenylphosphonium bromide (CPTPPB) and two commercially available phosphonium salts, tetraphenylphosphonium bromide (TPPB), and methyltriphenylphosphonium bromide (MTPPB) for the inhibition of zinc corrosion in 1 M HCl at 22 degrees C has been quantified using electrochemical techniques. The inhibitor concentration ranged from 1 x 10(-3) to 1 x 10(-7) mol dm(-3). The degree of corrosion inhibition for zinc in 1 M HCl at 22 degrees C was found to be in the order: CPTPPB > TTPPC > TPPB > PTPPC > BATPPC > MTPPB > ATPPB.
引用
收藏
页码:248 / 258
页数:11
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