Reaction kinetics of glycidyl trimethyl ammonium chloride and chitosan in 1-allyl-3-methylimidazolium chloride

被引：5
|
作者：
Li, Sipeng [1 ]
Li, Yan [1 ]
Yang, Xiaodeng [1 ]
机构：
[1] Qilu Univ Technol, Shandong Acad Sci, Shandong Prov Key Lab Mol Engn, Jinan 250353, Peoples R China
来源：
JOURNAL OF THE INDIAN CHEMICAL SOCIETY | 2021年 / 98卷 / 09期
关键词：
Quaternary ammonium chitosan; Modification; Reaction kinetics; 1-Allyl-3-methylimidazolium chloride; IONIC LIQUID; ANTIBACTERIAL ACTIVITY; BIOCOMPATIBILITY; QUATERNIZATION; SYNTHESIZE;
D O I：
10.1016/j.jics.2021.100129
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The modification of chitosan in ionic liquids through homogeneous reactions has advantages including shorter time and simple post-treatment and the generated chitosan derivatives have high degrees of subsititution and good reproducibility. In this paper, we studied the reaction kinetics of glycidyl trimethyl ammonium chloride and chitosan in 1-allyl-3-methylimidazolium chloride. Chitosan concentration, temperature, and reaction time were studied to determine their influence on reaction kinetics. The results indicated that reaction rate increased with increases of both chitosan concentration and temperature. A first-order kinetics equation was generated, where the relationship between reaction rate constant and temperature was determined.
引用
收藏
页数：5
相关论文
共 50 条
  • [21] Separation and recovery of cellulose from Zoysia japonica by 1-allyl-3-methylimidazolium chloride
    Li, Wei-Zun
    Ju, Mei-Ting
    Wang, Yan-Nan
    Liu, Le
    Jiang, Yang
    CARBOHYDRATE POLYMERS, 2013, 92 (01) : 228 - 235
  • [22] Esterification Mechanism of Bagasse Modified with Glutaric Anhydride in 1-Allyl-3-methylimidazolium Chloride
    Wang, Huihui
    Chen, Wei
    Zhang, Xueqin
    Liu, Chuanfu
    Sun, Runcang
    MATERIALS, 2017, 10 (08):
  • [23] Dual effects of dimethylsulfoxide on cellulose solvating ability of 1-allyl-3-methylimidazolium chloride
    Zhang, Chao
    Kang, Hongliang
    Li, Pingping
    Liu, Zhijing
    Zhang, Yijin
    Liu, Ruigang
    Xiang, Jun-feng
    Huang, Yong
    CELLULOSE, 2016, 23 (02) : 1165 - 1175
  • [24] Homogeneous benzoylation of cellulose in 1-allyl-3-methylimidazolium chloride: Hammett correlation, mechanism and regioselectivity
    Chen, Weiwei
    Feng, Ye
    Zhang, Mei
    Wu, Jin
    Zhang, Jinming
    Gao, Xia
    He, Jiasong
    Zhang, Jun
    RSC ADVANCES, 2015, 5 (72) : 58536 - 58542
  • [25] A novel method to prepare chemical fibers by plasticizing cotton with 1-allyl-3-methylimidazolium chloride
    Qiao, Xiaolong
    Ni, Shuzhen
    Lu, Hailong
    Wang, Xiu
    Zhou, Xiaofan
    INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 2021, 166 : 1508 - 1512
  • [26] Homogeneous tritylation of cellulose in 1-allyl-3-methylimidazolium chloride and subsequent acetylation: The influence of base
    Lv, Yuxia
    Chen, Yaliang
    Shao, Ziqiang
    Zhang, Renxu
    Zhao, Libin
    CARBOHYDRATE POLYMERS, 2015, 117 : 818 - 824
  • [27] Enhanced Dissolution of Cotton Cellulose in 1-Allyl-3-methylimidazolium Chloride by the Addition of Metal Chlorides
    Li, Xin
    Li, Haichao
    You, Tingting
    Chen, Xiaomei
    Ramaswamy, Shri
    Wu, Yu-Ying
    Xu, Feng
    ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2019, 7 (23): : 19176 - 19184
  • [28] 1-Allyl-3-methylimidazolium chloride plasticized-corn starch as solid biopolymer electrolytes
    Wang Ning
    Zhang Xingxiang
    Liu Haihui
    He Benqiao
    CARBOHYDRATE POLYMERS, 2009, 76 (03) : 482 - 484
  • [29] Plasticizing effect of 1-allyl-3-methylimidazolium chloride in cellulose acetate based polymer electrolytes
    Ramesh, S.
    Shanti, R.
    Morris, Ezra
    CARBOHYDRATE POLYMERS, 2012, 87 (04) : 2624 - 2629
  • [30] Analysis of the effect of 1-Allyl-3-Methylimidazolium chloride on thermodynamic stability, folding kinetics, and motional dynamics of horse cytochrome c
    Garg, Mansi
    Sharma, Deepak
    Kumar, Rajesh
    BIOPHYSICAL CHEMISTRY, 2022, 290
12345