Sequence Stereoisomerism in Calixarene-Based Pseudo[3]rotaxanes

被引：42
|
作者：
Talotta, Carmen [1 ]
Gaeta, Carmine [1 ]
Pierro, Teresa [1 ]
Neri, Placido [1 ]
机构：
[1] Univ Salerno, Dipartimento Chim & Biol, I-84084 Salerno, Italy
来源：
ORGANIC LETTERS | 2011年 / 13卷 / 08期
关键词：
ALPHA-CYCLODEXTRIN;
D O I：
10.1021/ol2005159
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Two calix[6]arene directional wheels can be ordered in the right stereosequence by their through-the-annulus threading with a rationally designed bis(benzylalkylammonium) axle. These stereoisomeric pseudo[3]rotaxanes can be considered as a minimal "informational system" because the "written information" on the thread is transferred to a specific sequence stereoisomer.
引用
收藏
页码：2098 / 2101
页数：4
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