Synthesis and structure of N,N'-diaryl derivatives of trans-1,2-diaminocyclohexane

被引：0

作者：

Kwit, M ^{[1
]}

Kubicki, M ^{[1
]}

Borowiak, T ^{[1
]}

Gawronski, J ^{[1
]}

机构：

[1] Adam Mickiewicz Univ Poznan, Dept Chem, PL-60780 Poznan, Poland

来源：

POLISH JOURNAL OF CHEMISTRY | 2003年 / 77卷 / 11期

关键词：

trans-1,2-diaminocyclohexane; palladium; N-arylation; conformation; circular dichroism;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Synthesis of NN'-diaryl derivatives of trans-1,2-diaminocyclohexane (DACH) by palladium-catalyzed aromatic nucleophilic substitution reactions is described. The conformation of the N-acetylated NN'-diaryl derivatives of DACH has been studied by the computational, circular dichroism and X-ray diffraction methods. Reversal of the relative orientation of the N-aryl residues due to N-acetylation has been established.

引用

页码：1669 / 1682

页数：14

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