Conversion of NOx1- (x=2, 3) to NO using an oxygen-deficient polyoxovanadate-alkoxide cluster

被引：18
|
作者：
Petel, Brittney E. [1 ]
Matson, Ellen M. [1 ]
机构：
[1] Univ Rochester, Dept Chem, Rochester, NY 14627 USA
来源：
CHEMICAL COMMUNICATIONS | 2020年 / 56卷 / 04期
基金：
美国国家科学基金会;
关键词：
ELECTROCATALYTIC REDUCTION; ATOM TRANSFER; NITRIC-OXIDE; NITRATE REDUCTION; COMPLEXES; LIGAND; CHEMISTRY; PROTON; COPPER; BROWNS;
D O I：
10.1039/c9cc08230a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We report the activation of nitrogen-containing oxyanions using an oxygen-deficient polyoxovanadate-alkoxide cluster. Reduction of NO21- and NO31- results in near-quantitative oxygen atom transfer to the coordinatively unsaturated V-III ion, and selective formation of NO. These results provide insight into possible mechanisms of oxyanion reduction by polyoxometalates.
引用
收藏
页码：555 / 558
页数：4
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