Conversion of NOx1- (x=2, 3) to NO using an oxygen-deficient polyoxovanadate-alkoxide cluster

被引：18
|
作者：
Petel, Brittney E. [1 ]
Matson, Ellen M. [1 ]
机构：
[1] Univ Rochester, Dept Chem, Rochester, NY 14627 USA
来源：
CHEMICAL COMMUNICATIONS | 2020年 / 56卷 / 04期
基金：
美国国家科学基金会;
关键词：
ELECTROCATALYTIC REDUCTION; ATOM TRANSFER; NITRIC-OXIDE; NITRATE REDUCTION; COMPLEXES; LIGAND; CHEMISTRY; PROTON; COPPER; BROWNS;
D O I：
10.1039/c9cc08230a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We report the activation of nitrogen-containing oxyanions using an oxygen-deficient polyoxovanadate-alkoxide cluster. Reduction of NO21- and NO31- results in near-quantitative oxygen atom transfer to the coordinatively unsaturated V-III ion, and selective formation of NO. These results provide insight into possible mechanisms of oxyanion reduction by polyoxometalates.
引用
收藏
页码：555 / 558
页数：4
相关论文
共 50 条
  • [1] O2 Activation with a Sterically Encumbered, Oxygen-Deficient Polyoxovanadate-Alkoxide Cluster
    Meyer, Rachel L.
    Miro, Pere
    Brennessel, William W.
    Matson, Ellen M.
    INORGANIC CHEMISTRY, 2021, 60 (18) : 13833 - 13843
  • [2] Efficient Hole Transfer from CdSe Quantum Dots Enabled by Oxygen-Deficient Polyoxovanadate-Alkoxide Clusters
    Cogan, Nicole M. B.
    Mcclelland, Kevin P.
    Peter, Chari Y. M.
    Rodriguez, Chayan Carmenate
    Fertig, Alex A.
    Amin, Mitesh
    Brennessel, William W.
    Krauss, Todd D.
    Matson, Ellen M.
    NANO LETTERS, 2023, 23 (22) : 10221 - 10227
  • [3] Thermal conductivity of oxygen-deficient YBa2Cu3O6+x
    Inyushkin, AV
    Taldenkov, AN
    Uvarova, TG
    PHYSICAL REVIEW B, 1996, 54 (18): : 13261 - 13268
  • [4] Thermal conductivity of oxygen-deficient YBa2Cu3PO6+x
    Inyushkin, A. V.
    Taldenkov, A. N.
    Uvarova, T. G.
    Physical Review B: Condensed Matter, 54 (18/PT2):
  • [5] Cluster formation in oxygen-deficient La0.5Yb0.5Ba2Cu3Oy
    Guskos, N.
    Likodimos, V.
    Typek, J.
    Wabia, M.
    Fuks, H.
    Radiation Effects and Defects in Solids, 1999, 151 (01): : 121 - 129
  • [6] Cluster formation in oxygen-deficient La0.5Yb0.5Ba2Cu3Oy
    Guskos, N
    Likodimos, V
    Typek, J
    Wabia, M
    Fuks, H
    RADIATION EFFECTS AND DEFECTS IN SOLIDS, 1999, 151 (1-4): : 121 - 129
  • [7] X-RAY AND MOSSBAUER STUDIES OF OXYGEN-DEFICIENT SRFEXMO1-XO3-Y
    KAWACHI, M
    ABE, M
    NOMURA, S
    JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 1973, 34 (02) : 372 - 375
  • [8] Oxygen-deficient WO3-x spheres for electrochemical N2 oxidation to nitrate
    Zhang, Ying
    Xu, Tongxin
    Shang, Yabing
    Zhang, Guoxin
    Yan, Zi-Feng
    JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2023, 650 : 669 - 675
  • [9] SELECTIVE PLASMA OXIDATION OF OXYGEN-DEFICIENT YBA2CU3O7-X
    YOSHIDA, A
    TAMURA, H
    GOTOH, K
    IMAMURA, T
    HASUO, S
    AKIMITSU, J
    JOURNAL OF APPLIED PHYSICS, 1993, 73 (11) : 7549 - 7555
  • [10] MECHANISMS FOR THE PERSISTENT PHOTOCONDUCTIVITY OF OXYGEN-DEFICIENT YBA2CU3O6+X
    KUDINOV, VI
    PHYSICA B, 1994, 194 : 1187 - 1188
12345