An Efficient Synthesis of Chiral Alcohols via Catalytic Hydrogenation of Esters

被引：27

作者：

Ino, Yasunori ^{[1
]}

Kuriyama, Wataru ^{[1
]}

Ogata, Osamu ^{[1
]}

Matsumoto, Takaji ^{[1
]}

机构：

[1] Takasago Int Corp, Corp Res & Dev Div, Hiratsuka, Kanagawa 2540073, Japan

来源：

TOPICS IN CATALYSIS | 2010年 / 53卷 / 15-18期

关键词：

Ester; Hydrogenation; Homogeneous; Ruthenium; Catalyst; Chiral; Alcohol; Amino alcohol; Diol; ASYMMETRIC HYDROGENATION; STEREOSELECTIVE HYDROGENATION; KETONE HYDROGENATION; COMPLEXES; MECHANISM; LIGANDS;

D O I：

10.1007/s11244-010-9573-x

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A ruthenium complex was found to catalyze the hydrogenation of chiral esters without the loss of their optical purities under mild and neutral conditions. This method can avoid a violent quench step and an extraction step which accompany conventional reduction using metal hydride reagents such as sodium borohydride and lithium aluminum hydride.

引用

页码：1019 / 1024

页数：6

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