Synthesis of a 2D polymeric cluster {[NEt4] [Mo2O2S6Cu6I3-(4,4′-bipy)5]•MeOH•H2O}n with a significant improvement of optical limiting effect

被引：79
|
作者：
Zhang, QF
Niu, YY
Leung, WH
Song, YL
Williams, ID
Xin, XQ
机构：
[1] Hong Kong Univ Sci & Technol, Dept Chem, Kowloon, Hong Kong, Peoples R China
[2] Nanjing Univ, Inst Coordinat Chem, Nanjing 210093, Peoples R China
[3] Nanjing Univ, Dept Chem, Nanjing 210093, Peoples R China
[4] Harbin Inst Technol, Dept Phys, Harbin 150001, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2001年 / 12期
关键词：
D O I：
10.1039/b101929p
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The self-assembly reaction of the monomeric nest-shaped cluster [NEt4](2)[MoOS3Cu3I3] 1 Or twin nest-shaped cluster [NEt4](4)[Mo2O2S6Cu6I6] 2 With the bridging ligand 4,4'bipyridine (4,4'-bipy) gave a 2D polymeric cluster ([NEt4]-[Mo2O2S6Cu6I3(4,4'-bipy)(5)].MeOH.H2O)(2) 3, which exhibits a significant improvement of optical limiting effect in its nonlinear optical properties relative to 1 or 2.
引用
收藏
页码：1126 / 1127
页数：2
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