Synthesis of a 2D polymeric cluster {[NEt4] [Mo2O2S6Cu6I3-(4,4′-bipy)5]•MeOH•H2O}n with a significant improvement of optical limiting effect

被引：79
|
作者：
Zhang, QF
Niu, YY
Leung, WH
Song, YL
Williams, ID
Xin, XQ
机构：
[1] Hong Kong Univ Sci & Technol, Dept Chem, Kowloon, Hong Kong, Peoples R China
[2] Nanjing Univ, Inst Coordinat Chem, Nanjing 210093, Peoples R China
[3] Nanjing Univ, Dept Chem, Nanjing 210093, Peoples R China
[4] Harbin Inst Technol, Dept Phys, Harbin 150001, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2001年 / 12期
关键词：
D O I：
10.1039/b101929p
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The self-assembly reaction of the monomeric nest-shaped cluster [NEt4](2)[MoOS3Cu3I3] 1 Or twin nest-shaped cluster [NEt4](4)[Mo2O2S6Cu6I6] 2 With the bridging ligand 4,4'bipyridine (4,4'-bipy) gave a 2D polymeric cluster ([NEt4]-[Mo2O2S6Cu6I3(4,4'-bipy)(5)].MeOH.H2O)(2) 3, which exhibits a significant improvement of optical limiting effect in its nonlinear optical properties relative to 1 or 2.
引用
收藏
页码：1126 / 1127
页数：2
相关论文
共 50 条
  • [1] Synthesis, crystal structure of a zigzag cluster coordination polymer {(n-Bu4N)2[Mo2O2S6Cu6Br4(4,4′-bipy)3]•0.5H2O}n
    Liang Kai
    Ji Ya-Li
    Xian Chun-Ying
    Li Yi-Zhi
    Zheng He-Gen
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2008, 24 (09) : 1543 - 1545
  • [2] SynthesesandStructuresofTwoNewCobaltSupramolecularComplexes,[Co（4,4'-bipy）2（H2O）4]·[Co2（4,4'-bipy）3（H2O）8]·2TST·2（4,4'-bipy）·4H2Oand[Co（4,4'-bipy）2（H2O）4]DSNT·4,4'-bipy
    余昀仿
    韦永勤
    吴克琛
    结构化学, 2009, 28 (11) : 1519 - 1524
  • [3] Polymeric monovalent and divalent copper sulfates with 4.4′-bipyridine:: [CU2(SO4)(4,4′-bipy)2 • 6H2O]n and [CU(SO4)(4,4′-bipy)(H2O) • 0.5H2O]n
    Lah, N
    Leban, I
    INORGANIC CHEMISTRY COMMUNICATIONS, 2006, 9 (01) : 42 - 45
  • [4] SYNTHESIS, CRYSTAL-STRUCTURE AND NONLINEAR-OPTICAL PROPERTIES OF [NET4]4[CU6MO2S6O2BR2I4]
    HOU, HW
    XIN, XQ
    LIU, J
    CHEN, MQ
    SHU, S
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1994, (22): : 3211 - 3214
  • [5] Structural, thermal, and magnetic properties of three transition metal-4,4′-bipyridine coordination polymers:: [Ni(4,4′-bipy)3(H2O)2](ClO4)2•1.4(4,4′-bipy)•3(H2O); [Co(4,4′-bipy)3(H2O)2](ClO4)2•1.4(4,4′-bipy)•3(H2O); [Cu(4,4′-bipy)3(DMSO)2](ClO4)2•2(4,4′-bipy)
    Woodward, JD
    Backov, R
    Abboud, KA
    Ohnuki, H
    Meisel, MW
    Talham, DR
    POLYHEDRON, 2003, 22 (20) : 2821 - 2830
  • [6] Syntheses and Structures of Two New Cobalt Supramolecular Complexes, [Co（4,4'-bipy）2（H2O）4]·[Co2（4,4'-bipy）3（H2O）8]·2TST·2（4,4'-bipy）·4H2O and [Co（4,4'-bipy）2（H2O）4]DSNT·4,4'-bipy
    余昀仿
    韦永勤
    吴克琛
    Chinese Journal of Structural Chemistry, 2009, (11) : 1519 - 1524
  • [7] Syntheses and Structures of Two New Cobalt Supramolecular Complexes, [Co(4,4′-bipy)2(H2O)4]•[Co2(4,4′-bipy)3(H2O)8]•2TST•2(4,4′-bipy)•4H2O and [Co(4,4′-bipy)2(H2O)4]DSNT•4,4′-bipy
    Yu Yun-Fang
    Wei Yong-Qin
    Wu Ke-Chen
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2009, 28 (11) : 1519 - 1524
  • [8] The synthesis and crystal structure {[Co(4,4′-bipy)(ambdc)(H2O)2](4,4′-bipy)(DMF)}n
    He, HY
    Zhou, YL
    Zhu, LG
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2006, 22 (01) : 142 - 144
  • [9] Synthesis and crystal structure of {Cu2(pdc)2(4,4′-bipy)(H2O)•3H2O}2
    Wen, YH
    Zhang, J
    Qin, YY
    Li, ZH
    Yao, K
    Chen, YB
    Cheng, HK
    Yao, YG
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2004, 23 (09) : 1001 - 1004
  • [10] Synthesis and Crystal Structure of {Cu2（pdc）2（4,4'-bipy）(H2O)·3H2O}2
    WEN Yi-Hang ZHANG Jian QIN Ye-Yan LI Zhao-Ji KANG Yao CHEN Yu-Biao CHENG Jian-Kai YAO Yuan-Gen② (State Key Laboratory of Structural Chemistry
    结构化学, 2004, (09) : 1001 - 1004
12345