Preparation, Characterization, and Catalytic Behavior of Nanostructured Mesoporous CuO/ZrO2 Catalysts for Low-Temperature CO Oxidation

被引:4
|
作者
Huang, Jing [1 ]
Wang, Shu-Rong [1 ]
Wu, Shi-Hua [1 ]
机构
[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
关键词
CO oxidation; CuO; ZrO2; catalyst; mesoporous; GAS SHIFT REACTION; AU/ZRO2; CATALYSTS; OXIDE; STABILITY; ZIRCONIA; AEROGELS; SUPPORT; TITANIA; ZRO2; H-2;
D O I
10.1080/01932690903269636
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
High-surface area mesoporous 20mol% CuO/ZrO2 catalyst was prepared by a surfactant-assisted method of nanocrystalline particle assembly, and characterized by x-ray powder diffraction (XRD), N2 adsorption, transmission electron microscopy (TEM), H2-TPR, TG-DTA, and x-ray photoelectron spectra (XPS) techniques. The catalytic properties of the CuO/ZrO2 nanocatalysts calcined at different temperature were evaluated by low-temperature carbon monoxide oxidation using a CATLAB system. The results showed that these mesoporous nanostructured CuO/ZrO2 catalysts were very active for low-temperature CO oxidation and the CuO/ZrO2 catalyst calcined at 400 degrees C exhibited the highest catalytic activity.
引用
收藏
页码:1469 / 1473
页数:5
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