Advanced water treatment with manganese oxide for the removal of 17α-ethynylestradiol (EE2)

Municipal wastewater is supposed to be one of the most important sources of endocrine-disrupting compounds (EDCs) in water. Therefore, advanced treatments and cost-efficient techniques should be developed to prevent the spread of this type of pollution into the environment. In this view, experiments were conducted in which the removal of 17alpha-ethynylestradiol (EE2), a synthetic and persistent estrogen, from water was monitored in three upstream bioreactors (UBRs), filled with, respectively, sand, granulated activated carbon (GAC) and MnO2 granules. Tap water, spiked with 15,000 ng EE2/L was filtered through the reactors with a hydraulic retention time of approximately I h. The removal of EE2 in the sand, GAC and MnO2 reactors was, respectively, 17.3%, > 99.8% and 81.7%. The removal in the GAC reactor was mainly due to adsorption. The MnO2 reactor, however, removed significantly more EE2 than could be predicted from its adsorption capacity, probably thanks to its catalytic properties. These catalytic properties could make it a cost-efficient technique for the removal of EE2, but further research at more environmentally relevant concentrations is needed. (C) 2003 Elsevier Ltd. All rights reserved.