Electrochemical Trifluoromethylation of Thiophenols with Sodium Trifluoromethanesulfinate

被引：18

作者：

Zhu, Xing-Xing ^{[1
]}

Wang, Huai-Qin ^{[1
]}

Li, Chen-Guang ^{[1
]}

Xu, Xiao-Lan ^{[2
]}

Xu, Jun ^{[1
]}

Dai, Jian-Jun ^{[1
]}

Xu, Hua-Jian ^{[1
]}

机构：

[1] Hefei Univ Technol, Sch Chem & Chem Engn, Anhui Prov Key Lab Adv Catalyt Mat & React Engn, Sch Food & Biol Engn, Hefei 230009, Peoples R China

[2] Anhui Med Univ, Sch Med Sci, Hefei 230032, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2021年 / 86卷 / 22期

基金：

中国国家自然科学基金; 国家重点研发计划;

关键词：

ARYL BORONIC ACIDS; OXIDATIVE TRIFLUOROMETHYLTHIOLATION; MEDICINAL CHEMISTRY; SILVER(I) TRIFLUOROMETHANETHIOLATE; ORGANIC ELECTROSYNTHESIS; EFFICIENT SYNTHESIS; CATALYZED SYNTHESIS; FLUORINE; THIOLS; MILD;

D O I：

10.1021/acs.joc.0c02659

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We developed an electrochemical trifluoromethylation of thiophenols without the use of metal catalysts and oxidants. This reaction features mild reaction conditions, readily available substrate, as well as moderate to good yields. In addition, this protocol can be easily scaled up with moderate efficiency.

引用

页码：16114 / 16120

页数：7

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