197Au Mossbauer Spectroscopy of Au25(SG)18- Revisited

被引：6
|
作者：
Tsukuda, Tatsuya [1 ]
Negishi, Yuichi [2 ]
Kobayashi, Yasuhiro [3 ]
Kojima, Norimichi [4 ]
机构：
[1] Hokkaido Univ, Sect Catalyt Assemblies, Catalysis Res Ctr, Sapporo, Hokkaido 0010021, Japan
[2] Tokyo Univ Sci, Dept Appl Chem, Fac Sci, Shinjuku Ku, Tokyo 1628601, Japan
[3] Kyoto Univ, Inst Res Reactor, Kumatori, Osaka 5900494, Japan
[4] Univ Tokyo, Dept Basic Sci, Grad Sch Arts & Sci, Meguro Ku, Tokyo 1538902, Japan
来源：
CHEMISTRY LETTERS | 2011年 / 40卷 / 11期
关键词：
THIOLATED GOLD CLUSTERS; AU-25; CLUSTERS; KDA GOLD; PROTECTED AU-25; NANOPARTICLE; STABILITY; COMPLEXES;
D O I：
10.1246/cl.2011.1292
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Reanalysis of the Au-197 Mossbauer spectrum of Au-25(SG)(18)(-)(SG: glutathionate) based on the structure determined by single-crystal XRD analysis gave a reasonable fit, demonstrating that Au-197 Mossbauer spectroscopy is a powerful tool for predicting the structural motifs of thiolate-protected Au clusters.
引用
收藏
页码：1292 / 1293
页数：2
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