Chemical and structural characterization of oxide precipitates in heavily boron doped silicon by infrared spectroscopy and transmission electron microscopy

被引:0
|
作者
De Gryse, O [1 ]
Clauws, P [1 ]
Vanhellemont, J [1 ]
Lebedev, O [1 ]
Van Landuyt, J [1 ]
Simoen, E [1 ]
Claeys, C [1 ]
机构
[1] Univ Ghent, Dept Solid State Sci, B-9000 Ghent, Belgium
来源
HIGH PURITY SILICON VII, PROCEEDINGS | 2002年 / 2002卷 / 20期
关键词
D O I
暂无
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Infrared absorption spectra of oxygen precipitates in boron doped silicon with a boron concentration between 10(17) and 10(19) cm(-3) are analyzed, applying the spectral function theory of the composite precipitates. The aspect ratio of the platelet precipitates has been determined by transmission electron microscopy measurements. Our analysis shows that in samples with moderate doping levels (<10(18) B cm(-3)) SiOgamma precipitates are formed with stoichiometry as in the lightly doped case. In the heavily (>10(18) cm(-3)) boron doped samples, however, the measured spectra of the precipitates are consistent with a mixture of SiO2 and B2O3. with a volume fraction of B2O3 as high as 0.41 in the most heavily doped case.
引用
收藏
页码:183 / 194
页数:12
相关论文
共 50 条
  • [41] Phase transformation of manganese-oxide precipitates in copper studied with transmission electron microscopy
    Kooi, BJ
    De Hosson, JTM
    ACTA MATERIALIA, 1998, 46 (06) : 1909 - 1922
  • [42] Low-temperature infrared absorption measurement for oxygen concentration and precipitates in heavily-doped silicon wafers
    Koizuka, M
    Inaba, M
    YamadaKaneta, H
    DEFECTS IN ELECTRONIC MATERIALS II, 1997, 442 : 31 - 36
  • [43] Microscopic chemical characterization of epoxy resin with scanning transmission electron microscopy - electron energy-loss spectroscopy
    Huang, Hsin-Hui
    Miyata, Tomohiro
    Sato, Yohei K.
    Mizoguchi, Teruyasu
    Jinnai, Hiroshi
    Yoshida, Kaname
    MICRON, 2024, 180
  • [44] Oxide precipitate-induced dislocation generation in heavily boron-doped Czochralski silicon
    Ono, T
    Romanowski, A
    Asayama, E
    Horie, H
    Sueoka, K
    Tsuya, H
    Rozgonyi, GA
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1999, 146 (09) : 3461 - 3465
  • [45] Characterization of pure and doped zirconia nanoparticles with infrared transmission spectroscopy
    Qian, Z
    Shi, JL
    NANOSTRUCTURED MATERIALS, 1998, 10 (02): : 235 - 244
  • [46] Structural analysis of reduced graphene oxide by transmission electron microscopy
    Shalaby, A.
    Nihtianova, D.
    Markov, P.
    Staneva, A. D.
    Iordanova, R. S.
    Dimitriev, Y. B.
    BULGARIAN CHEMICAL COMMUNICATIONS, 2015, 47 (01): : 291 - 295
  • [47] Structural and spectroscopic characterization of large boron heterocyclic radicals: Matrix infrared spectroscopy and quantum chemical calculations
    Xu, Jiaping
    Dai, Chuan-Ming
    Xu, Xin
    Jian, Jiwen
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2024, 305
  • [48] Cathodoluminescence of silicon doped aluminum nitride with scanning transmission electron microscopy
    Hauwiller, Matthew R.
    Stowe, David
    Eldred, Timothy B.
    Mita, Seiji
    Collazo, Ramon
    Sitar, Zlatko
    LeBeau, James
    APL MATERIALS, 2020, 8 (09)
  • [49] STRUCTURAL AND CHEMICAL CHARACTERIZATION OF SEMICONDUCTOR INTERFACES BY HIGH-RESOLUTION TRANSMISSION ELECTRON-MICROSCOPY
    OURMAZD, A
    POINT AND EXTENDED DEFECTS IN SEMICONDUCTORS, 1989, 202 : 135 - 151
  • [50] The chemical composition changes of silicon and phosphorus in the process of native oxide formation of heavily phosphorus doped silicon
    Ying, WB
    Mizokawa, Y
    Kamiura, Y
    Kawamoto, K
    Yang, WY
    APPLIED SURFACE SCIENCE, 2001, 181 (1-2) : 1 - 14