catena-Poly[[[diapua[trans-3-(4-pyridyl)acrylato]samarium(III)]-di-μ-trans-3-(4-pyridyl)acrylato] dihydrate]

被引：3
|
作者：
Zhu, YJ
Chen, JX
Zhang, WH
Zhang, Y
Lang, JP [1 ]
机构：
[1] Suzhou Univ, Key Lab Organ Synth Jiangsu Province, Sch Chem & Chem Engn, Jiangsu 215006, Peoples R China
[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2005年 / 61卷
关键词：
D O I：
10.1107/S0108270105031471
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In the title compound, {[Sm(4-pya)3(H2O) 2]̇2H2O}n [4-pya is trans-3-(4-pyridyl) acrylate, C8H6NO2], each SmIII atom is ten-coordinated and has a bicapped square-antiprismatic coordination geometry. There is a crystallographic center of symmetry at the mid-point of the Sm⋯Sm line within each [Sm(4-pya)3(H2O) 2]2 dimer. Each dimer is interconnected by two pairs of bridging 4-pya ligands to form a one-dimensional chain. Neighboring chains are connected via hydrogen bonds to form a three-dimensional network. © 2005 International Union of Crystallography.
引用
收藏
页码：M491 / M493
页数：3
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