Cerium and lanthanum modified Pd/Al2O3 catalysts for methanol decomposition

被引:0
|
作者
Yang, C [1 ]
Ren, J [1 ]
Sun, YH [1 ]
机构
[1] Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China
关键词
rare earths; cerium; lanthanum; supported Palladium; methanol; decomposition; synergistic effect;
D O I
暂无
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
CeO2 improves the activity and selectivity of Pd/Al2O3 catalyst for methanol decomposition. The interaction between Pd and CeO2 was then proposed to result in the promoting effect. The selectivity of CO and Hz is significantly improved by addition of La2O3 to either Pd/Al2O3 or Pd/CeO2/Al2O3 catalysts. Moreover, a synergistic promotion between CeO2 and La2O3 on gamma -Al2O3 supported Pd catalysts was observed for the catalytic activity towards methanol decomposition into CO and H-2.
引用
收藏
页码:67 / 69
页数:3
相关论文
共 50 条
  • [31] Hydrogenation of Cinnamaldehyde over Pd/Al2O3 Catalysts Modified with Thiol Monolayers
    Karl R. Kahsar
    Stephanie Johnson
    Daniel K. Schwartz
    J. Will Medlin
    Topics in Catalysis, 2014, 57 : 1505 - 1511
  • [32] Sonochemical asymmetric hydrogenation of isophorone on proline modified Pd/Al2O3 catalysts
    Mhadgut, SC
    Bucsi, I
    Török, M
    Török, B
    CHEMICAL COMMUNICATIONS, 2004, (08) : 984 - 985
  • [33] Catalytic combustion of methane over Ni modified Pd/Al2O3 catalysts
    Todorova, Silviya
    Naydenov, Anton
    Velinova, Ralitsa
    Kolev, Hristo
    Larin, Alexander
    Karashanova, D.
    MATERIALS TODAY-PROCEEDINGS, 2022, 61 : 1212 - 1216
  • [34] Hydrogenation of Cinnamaldehyde over Pd/Al2O3 Catalysts Modified with Thiol Monolayers
    Kahsar, Karl R.
    Johnson, Stephanie
    Schwartz, Daniel K.
    Medlin, J. Will
    TOPICS IN CATALYSIS, 2014, 57 (17-20) : 1505 - 1511
  • [35] Nb-modified Pd/Al2O3 Catalysts for Benzene Catalytic Combustion
    He Zhanfeng
    Wang Dan
    Liu Tao
    Wang Huanyi
    Jiang Yi
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2014, 35 (01): : 92 - 97
  • [36] Methane oxidation over vanadium-modified Pd/Al2O3 catalysts
    Escandón, LS
    Ordóñez, S
    Díez, F
    Sastre, H
    CATALYSIS TODAY, 2003, 78 (1-4) : 191 - 196
  • [37] Alkali hydroxide-modified Ru/γ-Al2O3 catalysts for ammonia decomposition
    Bajus, S.
    Agel, F.
    Kusche, M.
    Bhriain, N. Ni
    Wasserscheid, P.
    APPLIED CATALYSIS A-GENERAL, 2016, 510 : 189 - 195
  • [38] Hydrogenation of vinylbenzenes on Pd-Tm/Al2O3 and Tm/Al2O3 catalysts
    Parvulescu, VI
    Parvulescu, V
    Macovei, D
    Frunza, L
    JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1997, 93 (09): : 1827 - 1835
  • [39] Methanol dehydration to dimethylether over Al2O3 catalysts
    Akarmazyan, Siranush S.
    Panagiotopoulou, Paraskevi
    Kambolis, Anastasios
    Papadopoulou, Christina
    Kondarides, Dimitris I.
    APPLIED CATALYSIS B-ENVIRONMENTAL, 2014, 145 : 136 - 148
  • [40] Preparation of Pd/Al2O3/Al catalysts for CO removal
    Li, XH
    An, LD
    KOREAN JOURNAL OF CHEMICAL ENGINEERING, 1998, 15 (05) : 563 - 565