In situ FTIR Study of Methanol to Hydrocarbons Conversion Process on HZSM-5 Zeolite

被引：3
|
作者：
Wang, Bin [1 ,2 ]
Zhang, Ying [2 ]
Guo, Guangsheng [1 ]
机构：
[1] Beijing Univ Chem Technol, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China
[2] Sinopec Beijing Res Inst Chem Ind, Beijing 100013, Peoples R China
来源：
APPLICATION OF CHEMICAL ENGINEERING, PTS 1-3 | 2011年 / 236-238卷
关键词：
HZSM-5; zeolite; methanol to hydrocarbon; in situ FTIR; Lewis acid site; ZSM-5;
D O I：
10.4028/www.scientific.net/AMR.236-238.958
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
The reaction process of methanol to hydrocarbons was studied by means of in situ FTIR spectroscopic technique. The interaction between methanol and HZSM-5 surface was determined under different reaction conditions. It was found that the Lewis acid sites on the HZSM-5 surface played an important role in the conversion of methanol to hydrocarbons. During the catalysis process, methanol was adsorbed on the Lewis acid sites through chemical bond which was stronger than the interaction between methanol and the Bronsted acid sites. The dehydration of methanol took place on the Lewis acid sites to form the intermediate, dimethyl ether. According to the experimental results, the elaborate mechanism of methanol to hydrocarbons conversion was discussed.
引用
收藏
页码：958 / +
页数：2
相关论文
共 50 条
  • [41] Conversion of isopropanol and mixed alcohols to hydrocarbons using HZSM-5 Catalyst in the MixAlco process
    Taco-Vasquez, Sebastian
    Holtzapple, Mark T.
    AICHE JOURNAL, 2013, 59 (07) : 2549 - 2557
  • [42] Influence of the desilication process on the acidity of HZSM-5 zeolite
    Rac, Vladislav
    Rakic, Vesna
    Miladinovic, Zoran
    Stosic, Dusan
    Auroux, Aline
    THERMOCHIMICA ACTA, 2013, 567 : 73 - 78
  • [43] Conversion of ethanol on HZSM-5 modified zeolite, according to data from in situ spectrokinetic studies
    Tret'yakov, V. F.
    Chan Thi Quynh Nhu
    Tret'yakov, K. V.
    Sil'chenkova, O. N.
    Matyshak, V. A.
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2013, 87 (06) : 941 - 944
  • [44] Conversion of ethanol on HZSM-5 modified zeolite, according to data from in situ spectrokinetic studies
    V. F. Tret’yakov
    Chan Thi Quynh Nhu
    K. V. Tret’yakov
    O. N. Sil’chenkova
    V. A. Matyshak
    Russian Journal of Physical Chemistry A, 2013, 87 : 941 - 944
  • [45] The catalytic properties evolution of HZSM-5 in the conversion of methanol to gasoline
    Zhu, Lingjun
    Yin, Shi
    Wang, Xiaoliu
    Liu, Yincong
    Wang, Shurong
    RSC ADVANCES, 2016, 6 (86): : 82515 - 82522
  • [46] STUDY OF PHENOL AND METHANOL ADSORPTION ON HZSM-5 ZEOLITE BY THE IR-SPECTROSCOPY METHOD
    PONOMARENKO, IY
    PAUKSHTIS, EA
    KOVAL, LM
    ZHURNAL FIZICHESKOI KHIMII, 1993, 67 (08): : 1726 - 1728
  • [47] Improvement of HZSM-5 catalytic performance by rice husk ash addition for methanol to hydrocarbons process
    Chotiwan, Siwaruk
    Somwongsa, Phuntinee
    Lao-ubol, Supranee
    Lao-auyporn, Pracha
    Attanatho, Lalita
    Laosombut, Teerawit
    Larpkiattaworn, Siriporn
    MATERIALS TODAY-PROCEEDINGS, 2019, 17 : 1354 - 1361
  • [48] In situ solid state NMR observation of the methanol-to-hydrocarbons (MTH) process over nanosized and microsized HZSM-5 zeolites
    Yan, ZM
    Ma, D
    Zhuang, JQ
    Liu, XC
    Liu, XM
    Han, XW
    Bao, XH
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2002, 4 (18) : 4602 - 4607
  • [49] Ethanol conversion to selective high-value hydrocarbons over Ni/HZSM-5 zeolite catalyst
    Liu, Chun-Yen
    Struwe, Kim
    Lee, Cheng-Hung
    Chuang, Haw-Yeu
    Sauer, Joerg
    Yu, Joseph Che-Chin
    Van-Huy Nguyen
    Huang, Chao-Wei
    Wu, Jeffrey C. S.
    CATALYSIS COMMUNICATIONS, 2020, 144
  • [50] Effect of Magnesium Oxide Modification on the Catalytic Performance of Nanoscale HZSM-5 Zeolite for the Conversion of Methanol to Propylene
    Mao Dong-Sen
    Guo Qiang- Sheng
    Meng Tao
    ACTA PHYSICO-CHIMICA SINICA, 2010, 26 (08) : 2242 - 2248
12345