A novel helical chainlike nickel(II) coordination polymer containing 1D trigonal channels with water molecule guests
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作者:
Xie, Chengzhi
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Tianjin Med Univ, Sch Pharmaceut Sci, Tianjin 300070, Peoples R China
Luoyang Normal Univ, Coll Chem & Chem Engn, Luoyang 471022, Peoples R ChinaTianjin Med Univ, Sch Pharmaceut Sci, Tianjin 300070, Peoples R China
Xie, Chengzhi
[1
,2
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Su, Qiaojuan
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Tianjin Med Univ, Sch Pharmaceut Sci, Tianjin 300070, Peoples R ChinaTianjin Med Univ, Sch Pharmaceut Sci, Tianjin 300070, Peoples R China
Su, Qiaojuan
[1
]
Li, Shaohua
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Tianjin Med Univ, Sch Pharmaceut Sci, Tianjin 300070, Peoples R ChinaTianjin Med Univ, Sch Pharmaceut Sci, Tianjin 300070, Peoples R China
Li, Shaohua
[1
]
Xu, Jingyuan
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Tianjin Med Univ, Sch Pharmaceut Sci, Tianjin 300070, Peoples R ChinaTianjin Med Univ, Sch Pharmaceut Sci, Tianjin 300070, Peoples R China
Xu, Jingyuan
[1
]
Wang, Liya
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Luoyang Normal Univ, Coll Chem & Chem Engn, Luoyang 471022, Peoples R ChinaTianjin Med Univ, Sch Pharmaceut Sci, Tianjin 300070, Peoples R China
Wang, Liya
[2
]
机构:
[1] Tianjin Med Univ, Sch Pharmaceut Sci, Tianjin 300070, Peoples R China
[2] Luoyang Normal Univ, Coll Chem & Chem Engn, Luoyang 471022, Peoples R China
A novel ID helical nickel coordination polymer, [Ni(TAU)(2)(4,4'-bipy)](n)center dot 2nH(2)O (TAU = taurine, 4,4'-bipy = 4,4'-bipyridine), was synthesized and its crystal structure has been determined by X-ray diffraction. Each helix interlinks with six adjacent helices through extensive hydrogen bonds to form 3D supramolecular structure, in which 1D trigonal microporous channels filled with water guest molecules exist within the polymer coils. The framework remains intact on removal of guest water molecules which is proved by XPRD and TGA. Variable temperature magnetic susceptibility indicates weak anti-ferromagnetic interactions between the Ni(II) ions. (C) 2010 Elsevier B.V. All rights reserved.
机构:
Department of Applied Chemistry, School of Science, Anhui Agricultural University
School of Chemistry and Chemical Engineering, Anhui University and Key Laboratory of Functional Inorganic Materials Chemistry of Anhui ProvinceDepartment of Applied Chemistry, School of Science, Anhui Agricultural University
甘小平
孔林
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School of Chemistry and Chemical Engineering, Anhui University and Key Laboratory of Functional Inorganic Materials Chemistry of Anhui ProvinceDepartment of Applied Chemistry, School of Science, Anhui Agricultural University
孔林
吴鹏
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School of Chemistry and Chemical Engineering, Anhui University and Key Laboratory of Functional Inorganic Materials Chemistry of Anhui ProvinceDepartment of Applied Chemistry, School of Science, Anhui Agricultural University
吴鹏
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吕晨
涂雨龙
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School of Chemistry and Chemical Engineering, Anhui University and Key Laboratory of Functional Inorganic Materials Chemistry of Anhui ProvinceDepartment of Applied Chemistry, School of Science, Anhui Agricultural University
涂雨龙
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陈怡欣
周虹屏
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School of Chemistry and Chemical Engineering, Anhui University and Key Laboratory of Functional Inorganic Materials Chemistry of Anhui ProvinceDepartment of Applied Chemistry, School of Science, Anhui Agricultural University
周虹屏
吴杰颖
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School of Chemistry and Chemical Engineering, Anhui University and Key Laboratory of Functional Inorganic Materials Chemistry of Anhui ProvinceDepartment of Applied Chemistry, School of Science, Anhui Agricultural University
吴杰颖
田玉鹏
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机构:
School of Chemistry and Chemical Engineering, Anhui University and Key Laboratory of Functional Inorganic Materials Chemistry of Anhui ProvinceDepartment of Applied Chemistry, School of Science, Anhui Agricultural University
机构:
South China Normal Univ, Sch Chem & Environm, Guangzhou Key Lab Mat Energy Convers & Storage, Guangzhou 510006, Guangdong, Peoples R ChinaSouth China Normal Univ, Sch Chem & Environm, Guangzhou Key Lab Mat Energy Convers & Storage, Guangzhou 510006, Guangdong, Peoples R China
Cheng, Qiu-Xia
Lan, Jin-Ji
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South China Normal Univ, Sch Chem & Environm, Guangzhou Key Lab Mat Energy Convers & Storage, Guangzhou 510006, Guangdong, Peoples R ChinaSouth China Normal Univ, Sch Chem & Environm, Guangzhou Key Lab Mat Energy Convers & Storage, Guangzhou 510006, Guangdong, Peoples R China
Lan, Jin-Ji
Chen, Ying-Qian
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South China Normal Univ, Sch Chem & Environm, Guangzhou Key Lab Mat Energy Convers & Storage, Guangzhou 510006, Guangdong, Peoples R ChinaSouth China Normal Univ, Sch Chem & Environm, Guangzhou Key Lab Mat Energy Convers & Storage, Guangzhou 510006, Guangdong, Peoples R China
Chen, Ying-Qian
Lin, Jia
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South China Normal Univ, Sch Chem & Environm, Guangzhou Key Lab Mat Energy Convers & Storage, Guangzhou 510006, Guangdong, Peoples R ChinaSouth China Normal Univ, Sch Chem & Environm, Guangzhou Key Lab Mat Energy Convers & Storage, Guangzhou 510006, Guangdong, Peoples R China
Lin, Jia
Reddy, R. Chenna Krishna
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South China Normal Univ, Sch Chem & Environm, Guangzhou Key Lab Mat Energy Convers & Storage, Guangzhou 510006, Guangdong, Peoples R ChinaSouth China Normal Univ, Sch Chem & Environm, Guangzhou Key Lab Mat Energy Convers & Storage, Guangzhou 510006, Guangdong, Peoples R China
Reddy, R. Chenna Krishna
Lin, Xiao-Ming
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South China Normal Univ, Sch Chem & Environm, Guangzhou Key Lab Mat Energy Convers & Storage, Guangzhou 510006, Guangdong, Peoples R ChinaSouth China Normal Univ, Sch Chem & Environm, Guangzhou Key Lab Mat Energy Convers & Storage, Guangzhou 510006, Guangdong, Peoples R China
Lin, Xiao-Ming
Cai, Yue-Peng
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South China Normal Univ, Sch Chem & Environm, Guangzhou Key Lab Mat Energy Convers & Storage, Guangzhou 510006, Guangdong, Peoples R ChinaSouth China Normal Univ, Sch Chem & Environm, Guangzhou Key Lab Mat Energy Convers & Storage, Guangzhou 510006, Guangdong, Peoples R China