Effects of trifluoroethanol as a co-solvent on the electrochemical oxidation of hardly oxidizable organic compounds

被引：9

作者：

Shirai, K

Hamamoto, T

Maki, T

Onomura, O

Kise, N

Aoyama, Y

Matsumara, Y

机构：

[1] Nagasaki Univ, Fac Pharmaceut Sci, Nagasaki 8528521, Japan

[2] Tottori Univ, Fac Engn, Dept Biotechnol, Tottori 6800945, Japan

[3] Kyoto Univ, Fac Engn, Dept Synthet Chem & Biol Chem, Kyoto 6068501, Japan

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 2001年 / 507卷 / 1-2期

关键词：

electrochemical reactions; oxidation; alkoxylation; solvent and solvent effects;

D O I：

10.1016/S0022-0728(01)00403-X

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

2,2,2-Trifluoroethanol was found to be a suitable co-solvent for the electrochemical oxidation of organic compounds such as cyclic ethers, gamma -butyrolactone derivatives, primary alcohols, and toluenes substituted with electron-withdrawing groups, all of which were resistant toward oxidation in methanol. The oxidation products could be utilized as worthwhile synthetic intermediates. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：191 / 197

页数：7

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