Selective Formic Acid Synthesis from Nanoscale Electrochemistry

被引：23

作者：

Hoeckendorf, Robert F. ^{[2
]}

Siu, Chi-Kit ^{[1
]}

van der Linde, Christian ^{[2
]}

Balaj, O. Petru ^{[2
]}

Beyer, Martin K. ^{[2
]}

机构：

[1] City Univ Hong Kong, Dept Biol & Chem, Kowloon Tong, Hong Kong, Peoples R China

[2] Univ Kiel, Inst Phys Chem, D-24098 Kiel, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 44期

关键词：

carbon dioxide activation; hydrogen storage; hydrogen transfer; ion-molecule reactions; nanocalorimetry; AQUEOUS HYDROGENCARBONATE SOLUTION; TRANSITION-METAL COMPLEXES; CARBON-DIOXIDE; GAS-PHASE; ELECTROLYTIC REDUCTION; CLUSTER ANIONS; PHOTOELECTRON-SPECTROSCOPY; ELECTRONIC ISOMERS; CO2; IONS;

D O I：

10.1002/anie.201004134

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hydrogen-atom transfer from a thiol group to the CO2 radical anion is a fast and selective downhill process in a gas-phase water cluster. This suggests that placing a thiol group near the site of electron transfer to CO2 in a nanostructured electrochemical environment allows the selective formation of formic acid (see picture; dark gray C, light gray H, red O, yellow S). © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：8257 / 8259

页数：3

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