Carboxylation of phenylacetylene by carbon dioxide on heterogeneous Ag-containing catalysts

被引：15
|
作者：
Finashina, E. D. [1 ]
Kustov, L. M. [1 ,2 ]
Tkachenko, O. P. [1 ]
Krasovskiy, V. G. [1 ]
Formenova, E. I. [1 ]
Beletskaya, I. P. [2 ]
机构：
[1] Russian Acad Sci, ND Zelinsky Inst Organ Chem, Moscow 119991, Russia
[2] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119992, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2014年 / 63卷 / 12期
基金：
俄罗斯基础研究基金会;
关键词：
catalytic carboxylation of phenylacetylene; carbon dioxide; TERMINAL ALKYNES; OXIDE CATALYSTS; CO2; ZEOLITES; MONOXIDE;
D O I：
10.1007/s11172-014-0794-1
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A possibility of using heterogeneous catalysts with a low silver content for the direct carb-oxylation of phenylacetylene by carbon dioxide was demonstrated. A comparative study of the efficiency of the heterogeneous Ag-containing catalysts on different oxide supports (F-gamma-Al2O3, gamma-Al2O3, TiO2, SiO2) revealed that phenylpropiolic acid in the highest yield (62.1%) was achieved on the 0.5% Ag/F-Al2O3 catalysts.
引用
收藏
页码：2652 / 2656
页数：5
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