On the dynamics of coupled Bohmian and phase-space variables: A new hybrid quantum-classical approach

被引:40
|
作者
Burghardt, I
Parlant, G
机构
[1] Ecole Normale Super, Dept Chim, F-75231 Paris 05, France
[2] Univ Montpellier 2, Lab Struct & Dynam Syst Mol & Solides UMR 5636, F-34095 Montpellier 05, France
来源
JOURNAL OF CHEMICAL PHYSICS | 2004年 / 120卷 / 07期
关键词
D O I
10.1063/1.1647059
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A new approach to the coupling of quantum and classical dynamics is developed, by combining a hydrodynamic, Bohmian description for the quantum subsystem with a Liouville-space description for the classical subsystem. To this end, partial hydrodynamic moments are introduced, the dynamics of which is determined by a hierarchy of equations derived from the quantum Liouville equation. We focus on pure states (wave functions) and introduce a trajectory representation in a hybrid hydrodynamic-Liouvillian phase space. The interleaved trajectory dynamics is guided by a new type of quantum force. For illustration, we consider a pair of bilinearly coupled harmonic oscillators, for which the method is exact. (C) 2004 American Institute of Physics.
引用
收藏
页码:3055 / 3058
页数:4
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