The synthesis and crystal structures of two μ-oxo iron(III) porphyrin complexes

被引：1

作者：

Fan, Yingying

Li, Jianfeng ^{[1
]}

机构：

[1] Univ Chinese Acad Sci, CAS Ctr Excellence Topol Quantum Computat, Coll Mat Sci & Optoelect Technol, Beijing 101408, Peoples R China

来源：

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES | 2021年 / 25卷 / 10N12期

基金：

中国国家自然科学基金;

关键词：

mu-oxo iron porphyrin; single-crystal structure; UV-vis; IR; CYTOCHROME-C-OXIDASE; MAGNETIC CIRCULAR-DICHROISM; PICKET-FENCE PORPHYRINS; ACTIVE-SITE; MOLECULAR STEREOCHEMISTRY; HYDROGEN-BONDS; MODELS; HEME; BINDING; MONONUCLEAR;

D O I：

10.1142/S1088424621500838

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two mu-oxo iron(III) porphyrin complexes, mu-oxo-bis[meso-tetra-alpha,alpha,alpha,alpha-(o-nicotinamidophenyl)porphinatoiron(III)] ([Fe(TPyPP)](2)O) and its copper adduct ([Fe(TPyPP)(CuCl)](2)O[CF3SO3](2)), which are derived from Gunter's porphyrin model for cytochrome c oxidase are reported. The two complexes were isolated and characterized by single crystal X-ray diffraction, UV-vis and IR spectroscopies. Crystal structural analysis including comparisons to mu-oxo analogues and Hirshfeld surface calculations revealed several noteworthy structural features i.e. the various picket orientations which are partially attributed to intra- and/or inter-molecular nonbonded interactions.

引用

页码：981 / 990

页数：10

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