Structure of host-guest assemblies involving interaction of cyclen with diphenylphosphinic and 4-tert-butylbenzoic acid

被引：2
|
作者：
Gasperov, Vesna [1 ]
Lindoy, Leonard F. [1 ]
Parkin, Andrew [1 ]
Turner, Peter [1 ]
机构：
[1] Univ Sydney, Sch Chem, Ctr Heavy Met Res, Sydney, NSW 2006, Australia
来源：
JOURNAL OF MOLECULAR STRUCTURE | 2007年 / 839卷 / 1-3期
基金：
澳大利亚研究理事会;
关键词：
tetra-azamacrocycle; host-guest adduct; hydrogen bond; proton transfer;
D O I：
10.1016/j.molstruc.2006.11.011
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The synthesis and characterisation by single crystal X-ray diffraction of 1:2 host-guest assemblies formed between the tetra-amine macrocycle 1,4,7,10-tetraazacyclododecane (cyclen) and diphenylphosphinic acid or 4-tert-butylbenzoic acid are reported. In each case strong hydrogen bonds associated with proton transfer from the acid species to two (trans) amino groups in the cyclen ring are observed. Both adducts are also associated with complex hydrogen bonded networks involving the secondary amines and water molecules, with each crystal structure containing five water molecules per asymmetric unit. (C) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码：132 / 136
页数：5
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