Meso-tetraalkyltetrabenzoporphyrins and their zinc complexes. Synthesis and properties

被引：2
|
作者：
Yakubov, L. A. [1 ]
Galanin, N. E. [1 ]
Shaposhnikov, G. P. [1 ]
Lebedeva, N. Sh. [2 ]
Mal'kova, E. A. [2 ]
机构：
[1] Ivanovo State Univ Chem Technol, Ivanovo 153000, Russia
[2] Russian Acad Sci, Inst Solut Chem, Ivanovo, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2008年 / 78卷 / 06期
基金：
俄罗斯基础研究基金会;
关键词：
Porphyrin; General Chemistry; Electronic Absorption Spectrum; Zinc Complex; Phthalimide;
D O I：
10.1134/S1070363208060273
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A number of meso-tetraalkyltetrabenzoporphyrin zinc complexes having alkyl substituents with different lengths were synthesized by reaction of excess phthalimide with zinc salts of aliphatic carboxylic acids. The corresponding free bases were obtained by treatment of the complexes with sulfuric acid. The spectral properties of the complexes and ligands and thermal stability of the former were studied.
引用
收藏
页码：1255 / 1259
页数：5
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