Nitrogen-rich porphyrinic metal-organic frameworks synthesized by postsynthetic metathesis: from inert material to active catalyst

被引：16

作者：

Liu, Dahuan ^{[1
,2
]}

Wang, Xuan ^{[1
]}

Chen, Ying-Pin ^{[1
,3
]}

Yuan, Shuai ^{[1
]}

Zhong, Chongli ^{[3
]}

Zhou, Hong-Cai ^{[1
,3
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA

[2] Beijing Univ Chem Technol, State Key Lab Organ Inorgan Composites, Beijing 100029, Peoples R China

[3] Texas A&M Univ, Dept Mat Sci & Engn, College Stn, TX 77842 USA

来源：

SCIENCE CHINA-CHEMISTRY | 2016年 / 59卷 / 08期

基金：

美国国家科学基金会;

关键词：

metal-organic frameworks; porous coordination network; post-synthetic metathesis; catalysis; tetrazolate; ENERGY-TRANSFER; CRYSTAL; LIGANDS; DESIGN; MOFS; CO2;

D O I：

10.1007/s11426-016-0060-3

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

With the aid of a postsynthetic metathesis method, an inert nitrogen-rich porphyrinic metal-organic framework can exhibit a high catalytic activity in one-pot deacetalization-Knoevenagel condensation reaction.

引用

页码：975 / 979

页数：5

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