Nitrogen-rich porphyrinic metal-organic frameworks synthesized by postsynthetic metathesis: from inert material to active catalyst

被引:16
|
作者
Liu, Dahuan [1 ,2 ]
Wang, Xuan [1 ]
Chen, Ying-Pin [1 ,3 ]
Yuan, Shuai [1 ]
Zhong, Chongli [3 ]
Zhou, Hong-Cai [1 ,3 ]
机构
[1] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA
[2] Beijing Univ Chem Technol, State Key Lab Organ Inorgan Composites, Beijing 100029, Peoples R China
[3] Texas A&M Univ, Dept Mat Sci & Engn, College Stn, TX 77842 USA
基金
美国国家科学基金会;
关键词
metal-organic frameworks; porous coordination network; post-synthetic metathesis; catalysis; tetrazolate; ENERGY-TRANSFER; CRYSTAL; LIGANDS; DESIGN; MOFS; CO2;
D O I
10.1007/s11426-016-0060-3
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
With the aid of a postsynthetic metathesis method, an inert nitrogen-rich porphyrinic metal-organic framework can exhibit a high catalytic activity in one-pot deacetalization-Knoevenagel condensation reaction.
引用
收藏
页码:975 / 979
页数:5
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