Determination of association constants for weak solute-solute complexes by nuclear magnetic resonance spectroscopy

被引：9

作者：

Ngowe, CO ^{[1
]}

Bishop, KD ^{[1
]}

McGuffin, VL ^{[1
]}

机构：

[1] Michigan State Univ, Dept Chem, E Lansing, MI 48824 USA

来源：

ANALYTICA CHIMICA ACTA | 2001年 / 427卷 / 01期

关键词：

nuclear magnetic resonance spectroscopy; association constants; van der Waals complexes; anthracene; dodecane;

D O I：

10.1016/S0003-2670(00)01180-6

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Standard methods for the determination of association constants by nuclear magnetic resonance spectroscopy are adapted for weak complexes that interact only by van der Waals forces. The association constants and the corresponding changes in Gibbs free energy are determined for the self-association of anthracene and the mixed association of anthracene with dodecane in deuterated methanol. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：137 / 142

页数：6

共 50 条

[21] Determination of the diffusion constants of dimethylsulfide and dimethylsulfoniopropionate by diffusion-ordered nuclear magnetic resonance spectroscopy
Spiese, Christopher E.
MARINE CHEMISTRY, 2018, 207 : 77 - 83
[22] NUCLEAR MAGNETIC RESONANCE IN COPPER ALLOYS-ELECTRON DISTRIBUTION AROUND SOLUTE ATOMS
ROWLAND, TJ
PHYSICAL REVIEW LETTERS, 1960, 4 (11) : 589 - 589
[23] CORRELATION OF NUCLEAR SPIN RESONANCE LINE WIDTHS WITH FORMATION CONSTANTS OF WEAK COMPLEXES
RECHNITZ, GA
ZAMOCHNICK, SB
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1964, 86 (14) : 2953 - &
[24] NUCLEAR MAGNETIC RESONANCE DETERMINATION OF ASSOCIATION CONSTANTS OF ELECTRON DONOR-ACCEPTOR COMPLEXES - EFFECT OF REFERENCE STANDARDS AND BEHAVIOUR OF MIXED DONORS
FOSTER, R
TWISELTO.DR
RECUEIL DES TRAVAUX CHIMIQUES DES PAYS-BAS, 1970, 89 (10): : 1020 - &
[25] Influence of solute dissociation constants on the optimum adsorption of weak electrolytes on activated carbons
Ume, JI
INTERNATIONAL JOURNAL OF ENVIRONMENT AND POLLUTION, 2005, 23 (02) : 215 - 222
[26] DETERMINATION OF ACTIVATION ENERGIES BY NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY
MARQUARD, FH
CHEMISTRY & INDUSTRY, 1967, (42) : 1788 - +
[27] DETERMINATION OF OPTICAL PURITY BY NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY
RABAN, M
MISLOW, K
TETRAHEDRON LETTERS, 1965, (48) : 4249 - &
[28] DETERMINATION OF FORMIC ACID BY NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY
BURAKEVICK, JV
ONEILL, J
ANALYTICA CHIMICA ACTA, 1971, 54 (03) : 528 - +
[29] SIMULTANEOUS DETERMINATION OF SEVERAL CHARGE-TRANSFER COMPLEX ASSOCIATION CONSTANTS USING NUCLEAR MAGNETIC RESONANCE
FOSTER, R
FYFE, CA
NATURE, 1967, 213 (5076) : 591 - &
[30] DETERMINATION OF ASSOCIATION CONSTANTS FOR TRIMETHYL-SULFONIUM IODIDE USING PROTON MAGNETIC-RESONANCE SPECTROSCOPY
COVINGTON, AK
HASSALL, ML
LANTZKE, IR
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS II, 1972, 68 : 1352 - +

← 1 2 3 4 5 →