Hydrogen storage properties and neutron scattering studies of Mg2(dobdc)-a metal-organic framework with open Mg2+ adsorption sites

被引：166
|
作者：
Sumida, Kenji [2 ,3 ]
Brown, Craig M. [1 ]
Herm, Zoey R. [2 ,3 ]
Chavan, Sachin [4 ,5 ]
Bordiga, Silvia [4 ,5 ]
Long, Jeffrey R. [2 ,3 ]
机构：
[1] Natl Inst Stand & Technol, Ctr Neutron Res, Gaithersburg, MD 20899 USA
[2] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
[3] Lawrence Berkeley Natl Lab, Div Mat Sci, Berkeley, CA 94720 USA
[4] Univ Turin, IFM, Dept Chem, I-10135 Turin, Italy
[5] Univ Turin, NIS Ctr Excellence, I-10135 Turin, Italy
来源：
CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 04期
关键词：
CARBON-DIOXIDE; COORDINATION POLYMER; ADSORBED HYDROGEN; SURFACE-AREAS; H-2; TEMPERATURE; DIFFUSION; BINDING; DESIGN; PORES;
D O I：
10.1039/c0cc03453c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The hydrogen storage properties of Mg-2(dobdc) (dobdc(4-) = 2,5-dioxido-1,4-benzenedicarboxylate), a metal-organic framework possessing hexagonal one-dimensional channels decorated with unsaturated Mg2+ coordination sites, have been examined through low-and high-pressure adsorption experiments, infrared spectroscopy, and neutron scattering studies.
引用
收藏
页码：1157 / 1159
页数：3
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