Hydrogen storage properties and neutron scattering studies of Mg2(dobdc)-a metal-organic framework with open Mg2+ adsorption sites

被引：166

作者：

Sumida, Kenji ^{[2
,3
]}

Brown, Craig M. ^{[1
]}

Herm, Zoey R. ^{[2
,3
]}

Chavan, Sachin ^{[4
,5
]}

Bordiga, Silvia ^{[4
,5
]}

Long, Jeffrey R. ^{[2
,3
]}

机构：

[1] Natl Inst Stand & Technol, Ctr Neutron Res, Gaithersburg, MD 20899 USA

[2] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

[3] Lawrence Berkeley Natl Lab, Div Mat Sci, Berkeley, CA 94720 USA

[4] Univ Turin, IFM, Dept Chem, I-10135 Turin, Italy

[5] Univ Turin, NIS Ctr Excellence, I-10135 Turin, Italy

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 04期

关键词：

CARBON-DIOXIDE; COORDINATION POLYMER; ADSORBED HYDROGEN; SURFACE-AREAS; H-2; TEMPERATURE; DIFFUSION; BINDING; DESIGN; PORES;

D O I：

10.1039/c0cc03453c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The hydrogen storage properties of Mg-2(dobdc) (dobdc(4-) = 2,5-dioxido-1,4-benzenedicarboxylate), a metal-organic framework possessing hexagonal one-dimensional channels decorated with unsaturated Mg2+ coordination sites, have been examined through low-and high-pressure adsorption experiments, infrared spectroscopy, and neutron scattering studies.

引用

页码：1157 / 1159

页数：3

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